If you piggyback the PS pump off the alternator pulley so long as both groves on the alternator pulley are the same it has no effect on the math.
The PS pump will turn just as fast or slow as it would if it were belt driven directly off the crankshaft pulley.
I had some difficulty with the fan belt wanting to slip on the alternator pulley with the setup you describe. If the alternator pulley were bigger that would help..
Grigg