I've sampled crankcase gases with a 4-gas exhaust analyzer. Lots of CO2, and some unburned hydrocarbons, mostly. Very little carbon monoxide, and just about "normal atmosphere" O2 levels. I've also used an exhaust anaalyzer to test the vapors in a cooling system for CO and hydrocarbons, looking for head gasket leaks. Just be VERY careful not to suck up coolant into the tailpipe probe when you hold it over the radiator cap opening- - - -it severely damages the sensors in the machine if you do!
Jerry