I think you're the first person to ask about different valve sizes for the 235! This isn't a common upgrade for these engines - for most questions asked about how to get a high performance out of a 235, the answer is: replace with a 250 or 292.
That doesn't mean it's not impossible. I would say your best bet would be to find a competent local machine shop and take the head and valves in and ask what they can do, and how much it would cost. You should be able to find stock parts, but it will cost some extra in labor.
It's possible the shop will be able to find a larger valve with the same length and stem, and machine a larger seat into the head. Maybe the 250 valves are a good match, I really don't know. They can flip through their books and find a match.
The most limiting factor will probably be the distance between the intake and exhaust seats. For my Austin-Healey they make special "figure 8" valve seats to help prevent the seats falling out when they're too close. [You never know, the Healey engine is pretty close in size and displacement to a 250, that actually might be a source of parts.

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You might want to consider just enlarging the exhaust for best perf increase. They probably need new seats anyway. Can probably do that without worrying about the seats falling out.
How large of valves will probably depend on the head, so it might be interesting to find an old "dead" 235 head, saw it in pieces, and see how much room you really have to work with before you breach the water jacket.
There shouldn't be a problem with piston-to-valve clearance, should be no different than a stock valve due to the vertical operation so have them grind up a custom cam to your specs depending on what you want. More torque, more HP, etc. Maybe they have an off the shelf 235 cam that meets your needs == less money.
Don't forget to port and polish to really take advantage of those new larger valves.
Do this BEFORE the new seats are installed, but after the seat machining. Or have the shop do this. Really easy to get carried away and nick the seat surface. Not fun to pay for the valve job twice...
-Boyo