Replace it- - - -once a pushrod bends, it's very unlikely you'll ever be able to straighten it. If you want to try straightening, find a piece of plate glass just wide enough for both ends of the rod to hang off the edges, roll it over the glass, and gently tweak the rod until it rolls true. Pack a lunch- - - -you'll be there a while!
Then fix the sticky valve guide that caused the bend in the first place.
Jerry