I don't believe the 230/250 engines are "interference" engines, where the valves and pistons can get together even if a valve stays open at the wrong time. Yes, you can take the valve cover off (not the "head") and soak the valve stems with penetrating oil, then use a pry bar to work the valves up and down. There's even a special tool made to compress the valve springs on those stud-mounted rocker arms, but I've always made my own tool by welding a flat washer onto a discarded rocker arm and using a long tapered punch as a lever.
Jerry