Pull the valve cover and watch the valves for #6 cylinder as you rotate the crankshaft. When the last one in line (exhaust) opens and almost closes, you'll see the second valve from the rear (intake) begin to open. Now check to be sure the distributor rotor is pointed at #1. The ball and pointer align twice, once for #1 compression, and again when #6 is on the compression stroke. The only way to be sure you're in time on the correct cylinder is to watch the valve action.
Jerry